| Schauspieler | Rolle | Synchronsprecher | ||
| Robert Downey Jr. Robert Downey Jr. | Tony Stark / Iron Man | Tobias Meister Tobias Meister | ||
| Chris Evans Chris Evans | Steve Rogers / Captain America | Dennis Schmidt-Foß Dennis Schmidt-Foß | ||
| Chris Hemsworth Chris Hemsworth | Thor Odinson | Tommy Morgenstern Tommy Morgenstern | ||
| Mark Ruffalo Mark Ruffalo | Dr. Bruce Banner / Hulk | Norman Matt Norman Matt | ||
| Jeremy Renner Jeremy Renner | Clint Barton / Hawkeye | Gerrit Schmidt-Foß Gerrit Schmidt-Foß | ||
| Scarlett Johansson Scarlett Johansson | Natasha Romanoff / Black Widow | Luise Helm Luise Helm | ||
| Samuel L. Jackson Samuel L. Jackson | Nick Fury | Engelbert von Nordhausen Engelbert von Nordhausen | ||
| Don Cheadle Don Cheadle | Col. James 'Rhodey' Rhodes / War Machine | Dietmar Wunder Dietmar Wunder | ||
| Idris Elba Idris Elba | Heimdall | Marco Kröger Marco Kröger | ||
| Cobie Smulders | Agent Maria Hill | Christine Stichler | ||
| Aaron Taylor-Johnson Aaron Taylor-Johnson | Pietro Maximoff / Quicksilver | Constantin von Jascheroff Constantin von Jascheroff | ||
| Elizabeth Olsen Elizabeth Olsen | Wanda Maximoff / Scarlet Witch | Shandra Schadt Shandra Schadt | ||
| Andy Serkis Andy Serkis | Ulysses Klaue | Jörg Hengstler Jörg Hengstler | ||
| Anthony Mackie Anthony Mackie | Sam Wilson / The Falcon | Stefan Günther Stefan Günther | ||
| Paul Bettany Paul Bettany | Jarvis / Vision | Frank Schaff Frank Schaff | ||
| Julie Delpy Julie Delpy | Madame B | Andrea Aust Andrea Aust | ||
| Thomas Kretschmann | Baron Wolfgang von Strucker | Thomas Kretschmann | ||
| Claudia Kim | Dr. Helen Cho | Rubina Nath Rubina Nath | ||
| Ben Sakamoto | Cooper Barton | Elias Kunze | ||
| Stellan Skarsgard Stellan Skarsgard | Dr. Erik Selvig | Detlef Bierstedt Detlef Bierstedt | ||
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