| Schauspieler | Rolle | Synchronsprecher | ||
| David Tennant | Alexander Litvinenko | Matthias Scherwenikas Matthias Scherwenikas | ||
| Margarita Levieva | Marina Litvinenko | Katharina Spiering | ||
| Mark Bonnar | DSU Clive Timmons | Frank Röth Frank Röth | ||
| Barry Sloane | DS Jim Dawson | Björn Schalla Björn Schalla | ||
| Richard Pepper | DCI Duncan Ball | Tobias Kluckert Tobias Kluckert | ||
| Neil Maskell | DI Brent Hyatt | Gerrit Schmidt-Foß Gerrit Schmidt-Foß | ||
| Daniel Ryan | DAC Peter Clarke | Michael Iwannek Michael Iwannek | ||
| Kayla Meikle | DC Deborah Maxwell | Marie-Isabel Walke | ||
| Mark Ivanir | Alexander Goldfarb | Tobias Lelle Tobias Lelle | ||
| Temirlan Blaev | Anatoly Litvinenko (jung) | Jaron Müller-Schuch | ||
| Marcus Onilude | Aidan | Stefan Bräuler | ||
| James Esler | Anatoly Litvinenko (Teenager) | Domenic Redl | ||
| Radoslaw Kaim | Andrei Lugovoy | Mark Schmal | ||
| Simon Haines | Benjamin Swift | Fabian Oscar Wien Fabian Oscar Wien | ||
| Nikolai Tsankov | Boris Berezovsky | Marko Bräutigam Marko Bräutigam | ||
| Sam Marks | DC Oliver Gadney | Georgios Tzitzikos | ||
| Sam Troughton | DI Brian Tarpey | Bernhard Völger Bernhard Völger | ||
| Ian Conningham | Dr. Nick Gent | Alexander Hauff | ||
| Estella Daniels | Dr. Onome George | Ana Purwa | ||
| Zoe Telford | Ingrid Campbell | Antje Thiele Antje Thiele | ||
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